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Gas Equations and Gas Calculations (U.S.
Units)
Flowing Gas Density
The density of a gas is given by:
G is the specific gravity of the gas, which is given
by
P is the absolute pressure (PSIA) which is equal to line
pressure + local barometric pressure
Z is the gas compressibility factor
T is the absolute temperature (ºR) which is equal
to line temperature + 459.67ºF
The molecular weight of air is 28.9625, the molecular
weight of any given gas can be found from many reference sources. (e.g.)
Flow Measurement Engineering Handbook by Richard W. Miller or Perry and
Chilton's Chemical Engineer's Handbook.
The compressibility factor for any given gas may be calculated
using various methods or can be looked up in standard reference sources.
(e.g.) Flow Measurement Engineering Handbook by Richard W. Miller or Matheson
Gas Data Book.
Base Gas Density
The gas density equation remains the same but is referenced to what are
known as standard temperature and pressure conditions (STP). The reference
conditions used in general industry are 60ºF and 14.696 PSIA. The reference
conditions used vary from country to country and from industry to industry.
In the U.S. gas industry typical reference conditions are 60ºF and
14.73 PSIA.
Volumetric and Mass Flow
A flow rate expressed in volume units, (e.g.)ft³ per minute, is known
as volumetric flow. A flow rate expressed in mass units, (e.g.) lb per minute,
is known as mass flow. These flow units are linked together in the mass
conservation equation.
Converting Between Flowing and Base Units
By using the conservation of mass equation shown above we can easily convert
between flowing and base conditions. The following example illustrates
the procedure.
Example
Carbon dioxide is flowing through a pipe at a rate of 100 ft³ per
minute (ACFM), the line pressure is 80 PSI gauge and the line temperature
is 50ºF. The installation is situated at sea level. Calculate the
flow rate in standard ft³ per minute (SCFM)
From the Flow Measurement Engineering Handbook appendix D we find
that the molecular weight of air is 28.9625 and that of carbon dioxide
is 44.01. The barometric pressure at sea level is 14.696 PSIA.
From equation 2 we find that the S.G. of the gas is
The absolute pressure P = 80 + 14.696 = 94.696
The absolute temperature T = 50 + 459.67 = 509.67
The compressibility at pressures below 150 PSIA can be assumed to
be 1
Substituting the above values into equation 1 we get
Standard conditions are defined as 14.696 PSIA and 60ºF. To
find the density of carbon dioxide at these conditions we substitute the
values into equation 1. This gives a density of 0.12 lb per ft³.
By substituting flow and density values into equation 3, the conservation
of mass equation, we have the following.
Molecular Weights for Gas Mixtures
When gas mixtures are being considered there are no readily available
reference tables, it is then necessary to calculate the molecular weight
by using the simple combination procedure shown below.
Example
Calculate the molecular weight of the following gas mixture.
Hydrogen 10%
Nitrogen 20%
Carbon dioxide 30%
Oxygen 40%
| Gas Component
| Gas Fraction
| Component Molecular weight
| Fraction x MW (MW)
|
| Hydrogen
| 0.1
| 2.016
| 0.2016
|
| Nitrogen
| 0.2
| 28.013
| 5.6026
|
| Carbon dioxide
| 0.3
| 44.010
| 13.2030
|
| Oxygen
| 0.4
| 31.998
| 12.7992
|
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| Sum of MW products
| 31.8064
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Specific Heat of a Gas (Cp)
Sometimes it is necessary to calculate the heat content of a flowing gas
stream, in order to do this the specific heat of the gas must be known.
This data is easily obtained for common gasses by referring to the reference
books mentioned above. The units of specific heat are btu per lb ºF
The heat of the gas stream is given by:
Specific Heat of a Gas Mixture (Cp mix)
The specific heat of a gas mixture is calculated as follows:
Specific heat of mixture (Cp mix) =
(fraction of component 1 x Cp of component 1) + (fraction of component
2 x Cp of component 2) + .......etc.
Example
Calculate the specific heat of the gas mixture given earlier.
Cp of Hydrogen = 7.06 Btu/lb ºF
Cp of Nitrogen = 7.00 Btu/lb ºF
Cp of Carbon dioxide = 8.80 Btu/lb ºF
Cp of Oxygen = 7.04 Btu/lb ºF
Cp of mixture = (0.1 x 7.06) + (0.2 x 7.00) + (0.3 x 8.80) + (0.4
x 7.04) = 7.562 btu per lb ºF
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